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Acid Red 14

Acid Red 14 is an acid-class azo dye supplied as a water-soluble salt. It is predominantly used for dyeing and printing acid-dyeable fibers such as wool, silk and polyamide (nylon) and is valued for its bright red shades, predictable leveling behavior and reliable bath exhaustion under acidic conditions.

TRADE NAME:Acid Red B,Carmine B,Carmoisine

Key properties

  • Chemical class: Azo acid dye, supplied as a water-soluble salt.
  • Application: Designed for acid-dyed and protein fibers — wool, silk — and acid-dyeable polyamides (nylon).
  • Shade: Bright, vivid red with good tinting strength for blends and blends correction.
  • Solubility: High water solubility in acidic baths; easy to prepare stable dye baths.
  • Exhaustion: Good exhaustion and uptake on protein fibers when applied under recommended acidic conditions.
  • Leveling: Predictable leveling and uniformity when proper auxiliaries and dosing procedures are used.
  • Fastness profile: Generally good wet-fastness; lightfastness is moderate and can be improved with finishing treatments.
  • Compatibility: Compatible with common acid dye auxiliaries and leveling agents; not suitable as a pigment without fixation.
  • pH sensitivity: Dye uptake and shade depend strongly on bath pH — optimal performance in weakly to moderately acidic baths.
  • Handling & safety: Handle with standard PPE; avoid uncontrolled discharge to wastewater; follow local regulations for disposal.

Technical Specifications

  • ‍CAS NO: 3567-69-9,CI.NO: 14720
  • Molecular Formula: C20H12N2Na2O7S2
  • Molecular Weight: 502.43
  • Shade:Blue-ray red‍

Standard

Fiber

Soaping

Persperation Fastness

Oxygen bleaching

Light
Fastness

Fading

Stain

AATCC

Wool

3

3

2-3

1

3

ISO

Wool

2

5

3

1

3

Leveling(grade)

 

Displacement

 

Whitening

 

Solubility(g/L)

Metal ion effect(grade)

copper

iron

chromium

3~4

B

Good

200(100℃)

3

3

1~2

Colour Fastness Test

Test Methods

 fiber

Alkali resistance

Carbonization

Chlorination discoloration

Oxygen bleaching

Alkali fluff

Acid fluff

potting

soaping

Perspiration

Sun exposure

discolor

Staining

discolor

Staining

discolor

Staining

discolor

Staining

AATCC

wool

2

4

1

1

2~3

2~3

3

3

2~3

3

ISO

wool

3

4

1

1

1

4

3

2

1

1

2

5

3

3

Application:

The Barium salt can be used as organic pigment use. Also can be used in the manufacture color amylum, ink and used for leather, paper, soap, wood, electrical-controlled silver, medicine, biology and cosmetics shading.

Use condition:

  • ‍1. It is mainly used for dyeing wool in strong acid dyeing bath. It can be printed on wool, nylon and silk fabric. Its strontium salt can be used as organic pigment. It can also be used in the manufacture of lake, ink and leather, paper, soap, Coloring of wood, anodized aluminum, medical organisms and cosmetics.
  • 2. Wool dyeing is carried out in a strong acid bath, the pH value of the dyeing solution is adjusted to 2~4, and the Canadian dollar powder is used as a retarding agent. The highest dyeing temperature when using acetic acid as the dyeing agent is 95~100 °C; It is carried out in an acetic acid bath. When the wool is dyed in the same bath as the various fibers, the apparent color depth of the nylon is similar to that of the wool, the silk is slightly shallow, and the cellulose fibers are not stained.
  • 3. It is discolored by the influence of metal salt during dyeing, so this dye is generally not used as the main dye when dyeing red.


FAQ

What fibers are best dyed with Acid Red 14?

Acid Red 14 is optimized for protein fibers (wool, silk) and acid-dyeable polyamides such as nylon. It performs poorly on purely synthetic non-polar fibers unless special carriers or mordants are used.

What pH and bath conditions give the best exhaustion?

Acid dyes like Acid Red 14 typically give best uptake in an acidic bath. Aim for a weakly to moderately acidic pH (often around pH 3–5) and follow controlled temperature rise and dye addition to avoid streaking. Always run trials on your substrate and scale conditions to your equipment.

How can I deepen the shade without losing leveling?

To deepen shade while maintaining evenness, incrementally increase dye concentration and use a leveling auxiliary designed for acid dyes. Slow, controlled addition of dye and consistent bath agitation help prevent local overdosing. If using high concentrations, check for possible dye aggregation and adjust dispersing agents accordingly.

Is Acid Red 14 suitable for printing (paste) systems or only for exhaust dyeing?

Acid Red 14 can be formulated into printing pastes for wool and silk, but printing requires suitable binders and acidic fixation systems. For paste printing on nylon, ensure the paste pH and fixation step are compatible with the dye chemistry to secure acceptable fastness.

How can I improve lightfastness and wet-fastness after dyeing?

Lightfastness for many acid reds is moderate by nature. Consider post-dyeing treatments such as appropriate leveling/after-baths, application of lightfastness enhancing additives where compatible, and polymeric coating/finishing when product requirements demand higher durability. For wet-fastness, thorough rinsing and fixation/after-treatment with commercial wet-fastness auxiliaries are effective.

What auxiliaries are typically used with Acid Red 14?

Common auxiliaries include acid buffers to control bath pH, leveIing agents to improve uniformity, dispersing agents to reduce specking at higher concentrations, and mild oxidizing or fixing aids when recommended by the auxiliary supplier. Always verify compatibility on a lab scale.

Are there environmental or wastewater concerns I should plan for?

Acid dyes are water-soluble and can appear in effluent if not properly managed. Plan for dye removal or degradation in your wastewater treatment (adsorption, flocculation, biological treatment or advanced oxidation depending on local requirements) and minimize wash liquor volumes where feasible.

How should Acid Red 14 be stored and handled?

Store in a cool, dry place in tightly sealed containers away from direct sunlight and incompatible materials. Use appropriate PPE when handling powders or concentrated solutions, avoid inhalation and skin contact, and follow your facility’s safety data sheet (SDS) instructions.

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